The WelderDestiny Compass

Base Metal Essential Variable - Issue #025

Wednesday, June 21, 2017 / Perth Australia / By Niekie Jooste

In this edition of "The WelderDestiny Compass":

• Base Metal Type as Essential Variable
• Grouping In Welding Codes
• Chemical Composition Grouping
• Thermo-Mechanical Treatments
  

Base Metal Type as Essential Variable

Today we have the second of our series of articles relating to welding essential variables. We are tackling the "Base Metal Type" welding essential variable.

Each type of metal has very distinct properties, including how they respond to welding. It therefore makes sense that the base metal would be an essential variable within the welding codes.

A big problem is that the way in which materials are covered in material specifications and materials designation systems are not uniform. Some material designation systems are based purely on the chemical composition. Some are based on product type, such as pipe, casting or forging. Some are based on the end use of the material, such as pressure equipment, building structures or ships.

It should therefore be clear that different welding codes that focus on different welding scopes will deal with the base metal essential variable in different ways. We will try to get a big picture view of why this variable has an effect on our welding procedures.

If you would like to add your ideas to this week’s discussion, then please send me an e-mail with your ideas, (Send your e-mails to: compass@welderdestiny.com) or complete the comment form on the page below.

Now let's get stuck into this week’s topics...

Material Grouping in Welding Codes

Most welding codes will group base metals. The idea being that if you have demonstrated that you can successfully weld one of the base metals in the group, then that will be good enough to assume that you will get similar results when welding the other metals in that group. This saves us from having to qualify hundreds of different welding procedures on base metals that are essentially the same, or similar.

To achieve the outcome above, base metals are typically grouped on a combination of the following parameters:

• Chemical composition: Metals with similar chemical composition should give similar results when welding.
• Strength: Even though the nominal chemical compositions are similar, if the strength requirements for the base metals are different, then it is reasonable to expect that we need to display that we can achieve the required strength in the completed weld. Often the codes will include lower strength materials in the qualified range, when you qualify higher strength materials.
• Hardenability: Even minor alloy additions, or variations, in some metals can result in big differences in the hardness, strength and impact properties. A typical way in which this is expressed in carbon steels is by the use of a carbon equivalent. (CE) Click here to read more about hardenability and carbon equivalents...
• Thermo-Mechanical Treatments: Different heat treatments and mechanical treatments will result in different responses when welding.

As a general rule, the American codes, such as ASME IX, lists every material specification that is to be included in a group. In the case of ASME IX, these groups are termed "P" numbers. When impact properties are also specified, then an additional grouping is added. This is called the "group" number.

The European codes tend to rather give the rules whereby different materials can be grouped. They also tend to give tables that show typical material groupings, but if you follow their rules, you can theoretically decide for yourself into which group the base metal falls. Many of the "EN" and "ISO" welding codes (such as ISO 15614) tend to reference ISO/TR 15608 for the "grouping rules". Interestingly, these material groupings are very much in line with the ASME P number grouping system, and is primarily based on chemical composition and strength factors.

Chemical Composition Grouping

The broadest range of grouping in chemical composition will be based on the particular "alloy system" that is being welded. Typical alloy systems are:

• Ordinary Carbon Steels: P1 in ASME IX and Group 1 in ISO/TR 15608. (e.g. ASTM A106 pipe and A105 forgings)
• Low Alloy Steels: P2 - P5 in ASME IX and Group 2 - 5 in ISO/TR 15608. (e.g. Chrome Molybdenum steels)
• Austenitic Stainless Steels: P8 in ASME IX and Group 8 in ISO/TR 15608. (e.g. 304; 316 stainless steels)
• Duplex Stainless Steels: P10H in ASME IX and Group 10 in ISO/TR 15608. (e.g. Type 2205 or 2507 stainless steel.)
• Aluminium Alloys: P2X in ASME IX and Group 2X in ISO/TR 15608. Here the "2X" means 21; 22; 23 etc.
• Copper Alloys: P3X in ASME IX and Group 3X in ISO/TR 15608. Here the "3X" means 31; 32; 33 etc.
• Nickel Alloys: P4X in ASME IX and Group 4X in ISO/TR 15608. Here the "4X" means 41; 42; 43 etc.
• Titanium Alloys: P5X in ASME IX and Group 5X in ISO/TR 15608. Here the "5X" means 51; 52; 53 etc.
• Cast Irons: 7X in ISO/TR 15608. Here the "7X" means 71; 72; 73 etc. ASME IX does not classify the cast irons because ASME IX is a pressure equipment welding code, and it does not deal with welded cast iron pressure equipment. Given the ISO/TR 15608 is supposed to work across different product types, it includes the cast irons.

While it looks like there is a 1:1 correlation between ASME IX and ISO/TR 15608, this is not necessarily the case. There are some notable differences, especially in the case of the high alloy content Nickel Chrome alloys.

Thermo-Mechanical Treatments

A metal's final properties can be changed significantly by heat treatments (thermal treatments) such as:

• Annealing: Generally used for a process to get the material into its "softest" form.
• Quenching: A term used for rapidly cooling the material from a high temperature. For alloys that change phase when heating them up (e.g. carbon steels, ferritic or martensitic stainless steels, such as the 400 series)  this often results in a meta-stable phase (e.g. martensite) being formed that can typically be hard and brittle. For materials that do not change phase when heated up (e.g. austenitic stainless steels like 304 or 316) this quenching tends to ensure that unfavourable inter-metallic or carbide phases do not form at intermediate temperatures.
• Tempering: Often quenched materials are tempered to remove the excessive brittleness. We then call them quenched and tempered. (Q&T) Quenched and tempered materials like low alloy steels can have a very good balance of strength and toughness properties.
• Normalizing: A normalising treatment is generally achieved by taking the temperature of the metal to a temperature range above which a phase change occurs, and then removing it from the heat treatment furnace to cool in still air. In the case of carbon steels, this typically results in a refining of the grain size of the steel, leading to a favourable balance of strength and toughness.
• Precipitation Hardening: This is also often called "ageing". This is a typical treatment for aluminium alloys and precipitation hardened stainless steels. This is achieved by heating a previously quenched alloy to a somewhat elevated temperature for a period of time. At the elevated temperature, small precipitates form in the crystal structure. The presence of these precipitates result in a strengthening of the metal. Heating the material too much will result in "over ageing" where the precipitates grow too big, and loose much of their strengthening effect.

There are many more thermal treatments, but those mentioned above are sufficient for our present discussion.

It should be clear that a material that has enhanced properties due to a quenched and tempered thermal treatment will respond differently to welding than a material that was subjected to a precipitation hardening thermal treatment. For this reason, materials that have different thermal treatments are typically placed in different groups, or sub-groups, within the welding codes.

A metal's final properties can also be modified by mechanical treatments such as:

• Hot working: Hot working is generally defined as mechanical deformation of a material at a temperature high enough that the material microstructure will immediately respond to the deformation due to the mechanical treatment. As an example, a steel can be deformed at around 950°C in a forging operation. At that temperature, the steel has an austenitic structure. As the austenite grains are deformed by the mechanical treatment, the grains "recrystallise" to smaller grains. This treatment ultimately results in a steel with a finer grain structure, which has advantages in terms of increased strength and increased toughness.
• Cold working: Cold working is generally defined as a mechanical deformation of a metal at a temperature that is low enough that the microstructure cannot respond thermally to the deformation. As a general rule, cold working will result in a material that is stronger than one without the cold work. Excessive cold work can however result in a material that becomes very brittle.

Welding will generally result in a recrystallization of a cold worked material in the heat affected zone (HAZ) of the base metal. For this reason, materials with different mechanical treatments are placed in different material groupings or sub-groupings within the welding codes.

I hope this discussion has wet your appetite to explore the metallurgy aspects of welding further.

If you are interested in a more in-depth discussion on this topic, click here to explore it on the WelderDestiny website...

Yours in welding

Niekie Jooste

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